I find something odd regarding he Pillar of Skulls at least from what I learned from Planescape: Torment.
1) The pillar is made up of petitioners and has information about various topics. Petitioners forget everything they know when they die. How does the pillar gets it's information?
2) The pillar is on Avernus, first layer of Ba'ator (Plane of Lawful Evil). The pillar is made up of petitioners who caused someone's death by lying. Lying is chaotic. Why isn't the pillar in the Abyss?
Lying isn't chaotic. Devils do it all the time and 'loths would be the most chaotic beings in the multiverse if it were.
I gathered from Planscape cannon that it's a pile of Blood War trophies and that it has nothing to do with petitioners, but I may be wrong.