I certainly have my issues with the Slaad being to limited as exemplars of pure chaos, and being rather one-sided with their bias towards Evil. I know that they're described as being locked in that form by the Slaad lords because they were possibly too chaotic (Tales of the Infinite Staircase), or that they are possibly beings from multiple realities (4e, looks like something Cordell wrote).
Still they aren't exactly what I imagine for beings from a plane of Chaos, that's very good by itself as a plane of chaos. There's those monsters that were introduced in an issue of Dragon, shortly after the 3e MotP was released that I felt were interesting. But some were non-outsiders or things with alignments other than CN.
There's also the Proteans mainly covered in the Pathfinder Bestiary 2, and introduced as a (non-IP restricted) replacement for the Slaad in Pathfinder's Golarion Campaign. Who have some interesting ideas, even if they're mostly based around a snake-like form with some varieties. They at least have differing motivations.
I think Shemmy described the proteans as "slaadi on crack." Really, I'm happy with considering the proteans and slaadi as part of the same squamous race.
The Ogdoad in Egyptian mythology variously took the form of snakes, toads, or baboons.
My view, though, is that a froglike form is pretty much ideal for ever-shifting terrain of Limbo. Equally capable of walking on chunks of solid matter, swimming through liquid matter, leaping across chasms of gaseous matter, and hopping toward higher or lower islands of solidity, they're more appropriate than fishlike, humanlike, or avian creatures would be. Frogs have long been symbols of chaos; slaadi manage to be both creepy and more full of personality than a purely amorphous blob or indiscriminate shapeshifter with no fixed form of its own would be. Slaadi are likable, which ultimately matters more than the high concept.
I do thoroughly ignore any intimation that they might be more evil than good, though. They're chaotic, full of whims and caprice. They're equally likely to aid stranded travelers, guiding them to safety like batrachian dolphins,as they are to devour tasty-looking sapient morsels or lay eggs in their stomachs. To me that's a crucial part of their character; if they were merely ravenous monsters, they'd be boring.
The additional detail on slaadi background and personality in The Plane Below for fourth edition is very good, though. There's much in that book that can be adapted to Limbo. "...one controversial theory claims that all the stories are true because many alternate realities exist... Perhaps multiple universes collapsed into a single cosmos, and only slaads still remember the infinite possibilities of other timelines. Now trapped in a single reality, they rebel against its strictures and embrace chaos as a way of breaking free into the wider multiverse... slaads rail against order because it is their prison, and they embrace chaos as the key to freedom." This is pretty much explicitly tied to the idea of the True Slaadi from Tales from the Infinite Staircase - instead of infinite possibilities of slaadi being compressed into frogs, infinite possibilities of reality, in which the slaadi may have been any number of things, were compressed into one reality in which they were froglike beings, and the Spawning Stone might be the physical anchor that binds them.